{"created":"2023-05-25T05:23:06.570293+00:00","id":499,"links":{},"metadata":{"_buckets":{"deposit":"6fce73a2-a0d2-4c41-a69c-fc7f76ea5e8d"},"_deposit":{"created_by":3,"id":"499","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"499"},"status":"published"},"_oai":{"id":"oai:yamagata.repo.nii.ac.jp:00000499","sets":["34:36"]},"author_link":["2102","2106","2105","2104","2101","2103"],"item_3_alternative_title_18":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"ベンゾフリル水銀化合物の研究"}]},"item_3_alternative_title_19":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"ベンゾフリル スイギン カゴウブツ ノ ケンキュウ"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1974-02-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"203","bibliographicPageStart":"193","bibliographicVolumeNumber":"13","bibliographic_titles":[{"bibliographic_title":"山形大学紀要.工学"}]}]},"item_3_description_42":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Abstract　In the presence of sodium acetate, benzofuran and mercuric chloride in aqueous ethyl alcohol give 2-benzofurylmercuric chloride (2).2 is also prepared from coumarilic acid and mercuric chloride. 2 is converted by sodium thiosulfate into di-2-benzofuryimercury, and the reaction of 2 with acetyl chloride gives 2-benzofuryl methyl ketone identical with a specimen prepared from benzofuran, acetyl chloride, and stannic chloride. In the presence of lithium chloropalladite, the reactions of 2 with various olefins afford 2-benzofuryl-substituted olefins, accompanied by a smail amount of 2,2'-bibenzofuryl. Furthermore, in the presence of palladium salts, 2 is carbonylated in methanol to afford methyl coumarilate, di-2-benzofuryl ketone, and 2,2'-bibenzofuryl.　アルコール－水の混合溶液中酢酸ナトリウムの存在でベンゾフランと塩化第二水銀とを反応させると塩化－2－ベンゾフリル水銀(2)を生ずる。このものはまたクマリル酸と塩化第二水銀との反応によっても生ずる。2をチオ硫酸ナトリウムで還元するとジ－2－ベンゾフリル水銀となり，塩化アセチルと反応させると2－ベンゾフリルメチルケトンを生ずる。塩化パラジウム酸リチウムの存在で種々のオレフィンと反応させると，少量の2，2'－ビベンゾフリルを伴い， 2－ベンゾフリル置換オレフィン誘導体を生じた。さらにパラジウム塩の存在で，メタノール中一酸化炭素を反応させると，2，2'-ビベンゾフリルを伴いクマリル酸メチルエステルおよびジ－2－ベンゾフリルケトンを生じた。","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"2104","nameIdentifierScheme":"WEKO"}],"names":[{"name":"泉,  多恵子"}]},{"nameIdentifiers":[{"nameIdentifier":"2105","nameIdentifierScheme":"WEKO"}],"names":[{"name":"武田,  徹"}]},{"nameIdentifiers":[{"nameIdentifier":"2106","nameIdentifierScheme":"WEKO"}],"names":[{"name":"笠原,  晃"}]}]},"item_3_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"山形大学"}]},"item_3_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00242991","subitem_source_identifier_type":"NCID"}]},"item_3_text_33":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"ヤマガタ ダイガク"}]},"item_3_text_34":{"attribute_name":"別言語の出版者","attribute_value_mlt":[{"subitem_text_value":"Yamagata University"}]},"item_3_text_43":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_3_text_44":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_3_text_45":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_3_text_46":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Izumi,  Taeko"}],"nameIdentifiers":[{"nameIdentifier":"2101","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takeda,  Toru"}],"nameIdentifiers":[{"nameIdentifier":"2102","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kasahara,  Akira"}],"nameIdentifiers":[{"nameIdentifier":"2103","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-08-21"}],"displaytype":"detail","filename":"kiyoue-13-1-14-1_merged.pdf","filesize":[{"value":"538.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kiyoue-13-1-14-1_merged.pdf","url":"https://yamagata.repo.nii.ac.jp/record/499/files/kiyoue-13-1-14-1_merged.pdf"},"version_id":"0c54a5bf-5d82-4780-8976-d8104a9b4f49"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Studied on Benzofurylmercuric Compound","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Studied on Benzofurylmercuric Compound"}]},"item_type_id":"3","owner":"3","path":["36"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-09-06"},"publish_date":"2007-09-06","publish_status":"0","recid":"499","relation_version_is_last":true,"title":["Studied on Benzofurylmercuric Compound"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-25T07:17:05.313918+00:00"}